Electrochemical Degradation of Acridine Orange Dye at Ru-Doped Platinum Anode in Aqueous Solution
نویسندگان
چکیده
Degradation of acridine orange (AO) in aqueous solution by anodic oxidation with a Ru-doped Pt electrode (RuDPt) can be applied to the remediation of waste waters containing acridine orange. This environmentally friendly method decontaminates completely aqueous solutions of this dye. The COD value decreases to ~98% of the initial COD. Acridine orange (AO) is more rapidly removed in RuDPt electrode than in platinum electrode alone. The reaction was carried out in presence of dilute NaCl. The degradation rate increases with increasing current and follows I order kinetics up to 60% of the reaction. The rate increases with [NaCl] and decreases with [AO]. The dye is converted into CO2, H2O, NH4 and simpler inorganic salts.
منابع مشابه
Electrochemical Degradation of Congo Red from Aqueous Solution: Role of Graphite Anode as Electrode Material
The present work has been carried out to study the mechanism of electrochemical degradation of Congo red dye. Electrolysis has been carried out in a single-chamber electrochemical cell having graphite anode and platinum cathode in the presence of KCl as supporting electrolyte under amperostatic conditions. The potential across the electrodes has been adjusted so that a constant 30 mA current pa...
متن کاملPhotocatalytic degradation of methyl orange using ZnO and Fe doped ZnO: A comparative study
ZnO and 2% Fe doped ZnO photocatalytic nanomaterials were successfully synthesized by successive ionic layer adsorption and the reaction (SILAR) method. The characterizations of these nanomaterials were carried out using XRD, SEM and EDX techniques. XRD study shows that the samples have a hexagonal wurtzite crystal structure, size of which is in the range 21-23 nm. SEM shows nanoflakes or nano ...
متن کاملMulti element doped type-II heterostructure assemblies (N, S- TiO2/ZnO) for electrochemical crystal violet dye degradation
Herein, we report multi-element doped Type-II heterostructure assembly consists of N, S doped TiO2 and ZnO for electrochemical crystal violet dye degradation studies. Electrochemical measurements were performed on these synthesized N-S codoped TiO2/ZnO compositeheterostructured assemblies which are fabricated on Titanium (Ti) substrate. It was observed that a composite ele...
متن کاملNano Sized Ni/TiO2 @ NaX Zeolite with Enhanced Photocatalytic Activity
Nickel doped TiO2nano particles (1% w/w) were prepared and immobilized on NaX zeolite and after characterization by X-ray diffraction and scanning electron microscopy used as photo catalyts for degradation of orange G. The X-ray diffraction patterns show that the supported TiO2 are crystallized in anatase form and the intensity of the zeolite peaks decreases with the incre...
متن کاملStudies on quenching of fluorescence of reagents in aqueous solution leading to an optical chloride-ion sensor
The sensitivity of quinolineand acridine-type indicators towards the detection of low levels of chloride ions in aqueous and amine-doped media, by fluorescence quenching, is reported in this paper. Solution studies are based on the fluorescence of quinine sulphate, acridine and 3(6-methoxyquinolino) propanesulphonate (SPQ) and the fluorescence response of these indicators has been examined at d...
متن کامل